Pollutants and Sources

Christina



The two main sources of pollutants in urban areas are transportation (predominantly automobiles) and fuel combustion in stationary sources, including residential, commercial, and industrial heating and cooling and
coal-burning power plants. Motor vehicles produce high levels of carbon monoxides (CO) and a major source of hydrocarbons (HC) and nitrogen oxides (NOx). Whereas, fuel combustion in stationary sources is the dominant source of sulfur dioxide (SO2).



8.jpg

Pollutants

Carbon Dioxide

Carbon dioxide (CO2) is one of the major pollutants in the atmosphere. Major sources of CO2 are fossil fuels burning and deforestation. "The concentrations of CO2 in the air around 1860 before the effects of industrialization were felt, is assumed to have been about 290 parts per million (ppm). In the hundred years and more since then, the concentration has increased by about 30 to 35 ppm that is by 10 percent". (Breuer 67) Industrial countries account for 65% of CO2 emissions with the United States and Soviet Union responsible for 50%. Less developed countries (LDCs), with 80% of the world's people, are responsible for 35% of CO2 emissions but may contribute 50% by 2020. "Carbon dioxide emissions are increasing by 4% a year". (Miller 450)
In 1975, 18 thousand million tons of carbon dioxide (equivalent to 5 thousand million tons of carbon) were released into the atmosphere, but the atmosphere showed an increase of only 8 billion tons (equivalent to 2.2 billion tons of carbon". (Breuer 70) The ocean waters contain about sixty times more CO2 than the atmosphere. If the equilibrium is disturbed by externally increasing the concentration of CO2 in the air, then the oceans would absorb more and more CO2. If the oceans can no longer keep pace, then more CO2 will remain into the atmosphere. As water warms, its ability to absorb CO2 is reduced.
CO2 is a good transmitter of sunlight, but partially restricts infrared radiation going back from the earth into space. This produces the so-called greenhouse effect that prevents a drastic cooling of the Earth during the night. Increasing the amount of CO2 in the atmosphere reinforces this effect and is expected to result in a warming of the Earth's surface. Currently carbon dioxide is responsible for 57% of the global warming trend. Nitrogen oxides contribute most of the atmospheric contaminants.

N0X - nitric Oxide



  • Natural component of the Earth's atmosphere.
  • Important in the formation of both acid precipitation and photochemical smog (ozone), and causes nitrogen loading.
  • Comes from the burning of biomass and fossil fuels.
  • 30 to 50 million tons per year from human activities, and natural 10 to 20 million tons per year.
  • Average residence time in the atmosphere is days.
  • Has a role in reducing stratospheric ozone.

N20 - nitrous oxide

  • Natural component of the Earth's atmosphere.
  • Important in the greenhouse effect and causes nitrogen loading.
  • Human inputs 6 million tons per year, and 19 million tons per year by nature.
  • Residence time in the atmosphere about 170 years.
  • 1700 (285 parts per billion), 1990 (310 parts per billion), 2030 (340 parts per billion)

Sulfur and chlorofluorocarbons (CFCs)

Sulfur dioxide is produced by combustion of sulfur-containing fuels, such as coal and fuel oils. Also, in the process of producing sulfuric acid and in metallurgical process involving ores that contain sulfur. Sulfur oxides can injure man, plants and materials. At sufficiently high concentrations, sulfur dioxide irritates the upper respiratory tract of human beings because potential effect of sulfur dioxide is to make breathing more difficult by causing the finer air tubes of the lung to constrict. "Power plants and factories emit 90% to 95% of the sulfur dioxide and 57% of the nitrogen oxides in the United States. Almost 60% of the SO2 emissions are released by tall smoke stakes, enabling the emissions to travel long distances". (Miller 494) As emissions of sulfur dioxide and nitric oxide from stationary sources are transported long distances by winds, they form secondary pollutants such as nitrogen dioxide, nitric acid vapor, and droplets containing solutions of sulfuric acid, sulfate, and nitrate salts. These chemicals descend to the earth's surface in wet form as rain or snow and in dry form as a gases fog, dew, or solid particles. This is known as acid deposition or acid rain.

Chlorofluorocarbons (CFCs)

CFCs are lowering the average concentration of ozone in the stratosphere. "Since 1978 the use of CFCs in aerosol cans has been banned in the United States, Canada, and most Scandinavian countries. Aerosols are still the largest use, accounting for 25% of global CFC use". (Miller 448) Spray cans, discarded or leaking refrigeration and air conditioning equipment, and the burning plastic foam products release the CFCs into the atmosphere. Depending on the type, CFCs stay in the atmosphere from 22 to 111 years. Chlorofluorocarbons move up to the stratosphere gradually over several decades. Under high energy ultra violet (UV) radiation, they break down and release chlorine atoms, which speed up the breakdown of ozone (O3) into oxygen gas (O2).
Chlorofluorocarbons, also known as Freons, are greenhouse gases that contribute to global warming. Photochemical air pollution is commonly referred to as "smog". Smog, a contraction of the words smoke and fog, has been caused throughout recorded history by water condensing on smoke particles, usually from burning coal. With the introduction of petroleum to replace coal economies in countries, photochemical smog has become predominant in many cities, which are located in sunny, warm, and dry climates with many motor vehicles. The worst episodes of photochemical smog tend to occur in summer
.



Smog

To enlarge the image, click on it.
Photochemical smog is also appearing in regions of the tropics and subtropics where savanna grasses are periodically burned. Smog's unpleasant properties result from the irradiation by sunlight of hydrocarbons caused primarily by unburned gasoline emitted by automobiles and other combustion sources. The products of photochemical reactions includes organic particles, ozone, aldehydes, ketones, peroxyacetyl nitrate, organic acids, and other oxidants. Ozone is a gas created by nitrogen dioxide or nitric oxide when exposed to sunlight. Ozone causes eye irritation, impaired lung function, and damage to trees and crops. Another form of smog is called industrial smog.
This smog is created by burning coal and heavy oil that contain sulfur impurities in power plants, industrial plants, etc... The smog consists mostly of a mixture of sulfur dioxide and fog. Suspended droplets of sulfuric acid are formed from some of the sulfur dioxide, and a variety of suspended solid particles. This smog is common during the winter in cities such as London, Chicago, Pittsburgh. When these cities burned large amounts of coal and heavy oil without control of the output, large-scale problems were witnessed. In 1952 London, England, 4,000 people died as a result of this form of fog. Today coal and heavy oil are burned only in large boilers and with reasonably good control or tall smokestacks so that industrial smog is less of a problem. However, some countries such as China, Poland, Czechoslovakia, and some other eastern European countries, still burn large quantities of coal without using adequate controls.

Sources


Sources of air pollution refer to the various locations, activities or factors which are responsible for the releasing of pollutants in the atmosphere. These sources can be classified into two major categories which are:


Anthropogenic sources (human activity) mostly related to burning different kinds of fuel


  • "Stationary Sources" as smoke stacks of power plants, manufacturing facilities, municipal waste incinerators.Power plant is also used to refer to the engine in ships, aircraft and other large vehicles. Some prefer to use the term energy center because it more accurately describes what the plants do, which is the conversion of other forms of energy, like chemical energy, gravitational potential energy or heat energy into electrical energy.
  • "Mobile Sources" as motor vehicles, aircraft etc.Exhaust gases of automobiles and air crafts play a very important role in polluting the atmosphere.
  • Marine vessels, such as container ships or cruise ships, and related port air pollution.
  • Burning wood, fireplaces, stoves, furnaces and incinerators .
  • Oil refining, and industrial activity in general.
  • Chemicals, dust and controlled burn practices in agriculture and forestry management.
  • Fumes from paint, hair spray, varnish, aerosol sprays and other solvents.
  • Waste deposition in landfills, which generate methane. Military, such as nuclear weapons, toxic gases, germ warfare and rocketry.
Natural sources


  • Dust from natural sources, usually large areas of land with little or no vegetation.
  • Methane, emitted by the digestion of food by animals, for example cattle.
  • Radon gas from radioactive decay within the Earth's crust. Smoke and carbon monoxide from wildfires.
  • Volcanic activity, which produce sulfur, chlorine, and ash particulates.

Back to Air Pollution